In WinForms controls' overlapping (z-order, in other words) is adjusted easily by calling Control.BringToFront() and Control.SendToBack() methods. In Silverlight 2.0 the way to change z-order is not as straightforward although quite simple too.
First of all the default overlapping is controlled by the order in which controls appear in XAML: each subsequent element is placed on the top of the previous ones, like in the example below:

For changing the z-order in the XAML markup the Canvas.ZIndex attached property should be applied to elements. Higher property values place the control on the top of others:

The same effect can be achieved through the C# code by using Canvas.S ...